The heat of neutralization of a strong acid and a strong alkali is $57.0 \, kJ \, mol^{-1}$. The heat released when $0.5 \, mol$ of $HNO_3$ solution is mixed with $0.2 \, mol$ of $KOH$ is $.... \, kJ$.

  • A
    $57$
  • B
    $11.4$
  • C
    $28.5$
  • D
    $34.9$

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Comment on the thermodynamic stability of $NO_{(g)}$,given:
$\frac{1}{2} N_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow NO_{(g)}; \Delta_r H^{\ominus} = 90 \, kJ \, mol^{-1}$
$NO_{(g)} + \frac{1}{2} O_{2(g)} \rightarrow NO_{2(g)}; \Delta_r H^{\ominus} = -74 \, kJ \, mol^{-1}$

The $H_2O_{(g)}$ molecule dissociates as:
$(i)$ $H_2O_{(g)} \to H_{(g)} + OH_{(g)}; \Delta H = 490 \ kJ$
$(ii)$ $OH_{(g)} \to H_{(g)} + O_{(g)}; \Delta H = 424 \ kJ$
The average bond energy (in $kJ$) for water is

The reaction of methanol $(\Delta H_f^o = -238.7 \ kJ \ mol^{-1})$ with $2$-methylpropene produces methyl tert-butyl ether $(\Delta H_f^o = -313.6 \ kJ \ mol^{-1})$. Given the reaction: $(CH_3)_2C = CH_2 + CH_3OH \rightarrow (CH_3)_3C - OCH_3; \Delta H^o = -57.8 \ kJ \ mol^{-1}$,calculate the $\Delta H_f^o$ for $2$-methylpropene.

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For the reaction $H_{2(g)} + C_{2}H_{4(g)} \rightarrow C_{2}H_{6(g)}$,the enthalpy change is ....... $Kcal \, mol^{-1}$. Given bond energies: $H-H = 103$,$C-H = 99$,$C-C = 80$,and $C=C = 145 \, Kcal \, mol^{-1}$.

The enthalpies of combustion of cyclohexane $(C_6H_{12})$,cyclohexene $(C_6H_{10})$,and $H_2$ are $-3920, -3800$,and $-241 \, kJ \, mol^{-1}$ respectively. The heat of hydrogenation of cyclohexene is ...... $kJ \, mol^{-1}$.

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